Key Features
- Includes new chapter that introduces basic terms and concepts for a firm foundation of study
- Features clear explanations of complex topics and avoids complicated mathematical analysis
- Updated chapters with recent advances in combustion, fuel cells, and more
- Solutions manual will be provided for end-of-chapter problems
Chapter 1. Introduction and Revision
- 1.1. Thermodynamics
- 1.2. Definitions
- 1.3. Thermal Equilibrium and the Zeroth Law
- 1.4. Temperature Scales
- 1.5. Interactions between Systems and Surroundings
- 1.6. Concluding Remarks
- 1.7. Problems
Chapter 2. The Second Law and Equilibrium
- 2.1. Thermal Efficiency
- 2.2. Heat Engine
- 2.3. Second Law of Thermodynamics
- 2.4. The Concept of the Heat Engine: Derived by Analogy with a Hydraulic Device
- 2.5. The Absolute Temperature Scale
- 2.6. Entropy
- 2.7. Representation of Heat Engines
- 2.8. Reversibility and Irreversibility (first corollary of second law)
- 2.9. Equilibrium
- 2.10. Helmholtz Energy (Helmholtz Function)
- 2.11. Gibbs Energy
- 2.12. Gibbs Energy and Phases
- 2.13. Examples of Different Forms of Equilibrium Met in Thermodynamics
- 2.14. Concluding Remarks
- 2.15. Problems
Chapter 3. Engine Cycles and their Efficiencies
- 3.1. Heat Engines
- 3.2. Air-Standard Cycles
- 3.3. General Comments on Efficiencies
- 3.4. Reversed Heat Engines
- 3.5. Concluding Remarks
- 3.6. Problems
Chapter 4. Availability and Exergy
- 4.1. Displacement Work
- 4.2. Availability
- 4.3. Examples
- 4.4. Available and Non-available Energy
- 4.5. Irreversibility
- 4.6. Graphical Representation of Available Energy and Irreversibility
- 4.7. Availability Balance for a Closed System
- 4.8. Availability Balance for an Open System
- 4.9. Exergy
- 4.10. The Variation of Flow Exergy for a Perfect Gas
- 4.11. Concluding Remarks
- 4.12. Problems
Chapter 5. Rational Efficiency of Power Plant
- 5.1. The Influence of Fuel Properties on Thermal Efficiency
- 5.2. Rational Efficiency
- 5.3. Rankine Cycle
- 5.4. Examples
- 5.5. Concluding Remarks
- 5.6. Problems
Chapter 6. Finite Time (or Endoreversible) Thermodynamics
- 6.1. General Considerations
- 6.2. Efficiency at Maximum Power
- 6.3. Efficiency of Combined Cycle Internally Reversible Heat Engines when Producing Maximum Power Output
- 6.4. Practical Situations
- 6.5. More Complex Example of the Use of FTT
- 6.6. Concluding Remarks
- 6.7. Problems
Chapter 7. General Thermodynamic Relationships: for Single Component Systems or Systems of Constant Composition
- 7.1. The Maxwell Relationships
- 7.2. Uses of the Thermodynamic Relationships
- 7.3. Tds Relationships
- 7.4. Relationships between Specific Heat Capacities
- 7.5. The Clausius–Clapeyron Equation
- 7.6. Concluding Remarks
- 7.7. Problems
Chapter 8. Equations of State
- 8.1. Ideal Gas Law
- 8.2. Van der Waals Equation of State
- Problem
- 8.3. Law of Corresponding States
- 8.4. Isotherms or Isobars in the Two-phase Region
- 8.5. Concluding Remarks
- 8.6. Problems
Chapter 9. Thermodynamic Properties of Ideal Gases and Ideal Gas Mixtures of Constant Composition
- 9.1. Molecular Weights
- 9.2. State Equation for Ideal Gases
- 9.3. Tables of u(T) and h(T) Against T
- 9.4. Mixtures of Ideal Gases
- 9.5. Entropy of Mixtures
- 9.6. Concluding Remarks
- 9.7. Problems
Chapter 10. Thermodynamics of Combustion
- 10.1. Simple Chemistry
- 10.2. Combustion of Simple Hydrocarbon Fuels
- 10.3. Heats of Formation and Heats of Reaction
- 10.4. Application of the Energy Equation to the Combustion Process – a Macroscopic Approach
- 10.5. Combustion Processes
- 10.6. Examples
- 10.7. Concluding Remarks
- 10.8. Problems
Chapter 11. Chemistry of Combustion
- 11.1. Bond Energies and Heat of Formation
- 11.2. Energy of Formation
- 11.3. Enthalpy of Reaction
- 11.4. Concluding Remarks
Chapter 12. Chemical Equilibrium and Dissociation
- 12.1. Gibbs Energy
- 12.2. Chemical Potential, µ
- 12.3. Stoichiometry
- 12.4. Dissociation
- 12.5. Calculation of Chemical Equilibrium and the Law of Mass Action
- 12.6. Variation of Gibbs Energy with Composition
- 12.7. Examples of Significance of Kp
- 12.8. The Van't Hoff Relationship between Equilibrium Constant and Heat of Reaction
- 12.9. The Effect of Pressure and Temperature on Degree of Dissociation
- 12.10. Dissociation Calculations for the Evaluation of Nitric Oxide
- 12.11. Dissociation Problems with Two, or More, Degrees of Dissociation
- 12.12. Concluding Remarks
- 12.13. Problems
Chapter 13. Effect of Dissociation on Combustion Parameters
- 13.1. Calculation of Combustion Both with and without Dissociation
- 13.2. The Basic Reactions
- 13.3. The Effect of Dissociation on Peak Pressure
- 13.4. The Effect of Dissociation on Peak Temperature
- 13.5. The Effect of Dissociation on the Composition of the Products
- 13.6. The Effect of Fuel on Composition of the Products
- 13.7. The Formation of Oxides of Nitrogen
- 13.8. Concluding Remarks
Chapter 14. Chemical Kinetics
- 14.1. Introduction
- 14.2. Reaction Rates
- 14.3. Rate Constant for Reaction, k
- 14.4. Chemical Kinetics of NO
- 14.5. Other Kinetics-Controlled Pollutants
- 14.6. The Effect of Pollutants Formed Through Chemical Kinetics
- 14.7. Concluding Remarks
- 14.8. Problems
Chapter 15. Combustion and Flames
- 15.1. Introduction
- 15.2. Thermodynamics of Combustion
- 15.3. Explosion Limits
- 15.4. Flames
- 15.5. Concluding Remarks
- 15.6. Problems
Chapter 16. Reciprocating Internal Combustion Engines
- 16.1. Introduction
- 16.2. Further Considerations of Basic Engine Cycles
- 16.3. Spark-Ignition Engines
- 16.4. Diesel (Compression Ignition) Engines
- 16.5. Friction in Reciprocating Engines
- 16.6. Simulation of Combustion in Spark-Ignition Engines
- 16.7. Concluding Remarks
- 16.8. Problems
Chapter 17. Gas Turbines
- 17.1. The Gas Turbine Cycle
- 17.2. Simple Gas Turbine Cycle Analysis
- 17.3. Aircraft Gas Turbines
- 17.4. Combustion in Gas Turbines
- 17.5. Concluding Remarks
- 17.6. Problems
Chapter 18. Liquefaction of Gases
- 18.1. Liquefaction by Cooling – Method (i)
- 18.2. Liquefaction by Expansion – Method (ii)
- 18.3. Concluding Remarks
- 18.4. Problems
Chapter 19. Pinch Technology
- 19.1. Heat Transfer Network without a Pinch Problem
- 19.2. Step 1: Temperature Intervals
- 19.3. Step 2: Interval Heat Balances
- 19.4. Heat Transfer Network with a Pinch Point
- 19.5. Step 3: Heat Cascading
- 19.6. Problems
Chapter 20. Irreversible Thermodynamics
- 20.1. Definition of Irreversible or Steady-State Thermodynamics
- 20.2. Entropy Flow and Entropy Production
- 20.3. Thermodynamic Forces and Thermodynamic Velocities
- 20.4. Onsager's Reciprocal Relation
- 20.5. The Calculation of Entropy Production or Entropy Flow
- 20.6. Thermoelectricity – The Application of Irreversible Thermodynamics to a Thermocouple
- 20.7. Diffusion and Heat Transfer
- 20.8. Concluding Remarks
- 20.9. Problems
Chapter 21. Fuel Cells
- 21.1. Types of Fuel Cells
- 21.2. Theory of Fuel Cells
- 21.3. Efficiency of a Fuel Cell
- 21.4. Thermodynamics of Cells Working in Steady State
- 21.5. Losses in Fuel Cells
- 21.6. Sources of Hydrogen for Fuel Cells
- 21.7. Concluding Remarks
- 21.8. Problems
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