Advanced Thermodynamics for Engineers,
Edition 2
By D. Winterbone, FEng, BSc, PhD, DSc, FIMechE, MSAE and Ali Turan

Publication Date: 10 Feb 2015
Description
Advanced Thermodynamics for Engineers, Second Edition introduces the basic concepts of thermodynamics and applies them to a wide range of technologies. Authors Desmond Winterbone and Ali Turan also include a detailed study of combustion to show how the chemical energy in a fuel is converted into thermal energy and emissions; analyze fuel cells to give an understanding of the direct conversion of chemical energy to electrical power; and provide a study of property relationships to enable more sophisticated analyses to be made of irreversible thermodynamics, allowing for new ways of efficiently covering energy to power (e.g. solar energy, fuel cells). Worked examples are included in most of the chapters, followed by exercises with solutions. By developing thermodynamics from an explicitly equilibrium perspective and showing how all systems attempt to reach equilibrium (and the effects of these systems when they cannot), Advanced Thermodynamics for Engineers, Second Edition provides unparalleled insight into converting any form of energy into power. The theories and applications of this text are invaluable to students and professional engineers of all disciplines.

Key Features

  • Includes new chapter that introduces basic terms and concepts for a firm foundation of study
  • Features clear explanations of complex topics and avoids complicated mathematical analysis
  • Updated chapters with recent advances in combustion, fuel cells, and more
  • Solutions manual will be provided for end-of-chapter problems
About the author
By D. Winterbone, FEng, BSc, PhD, DSc, FIMechE, MSAE, Emeritus Professor, University of Manchester, UK and Ali Turan, Professor of Thermodynamics Power Generation, University of Manchester, Manchester, UK
Table of Contents

Chapter 1. Introduction and Revision

  • 1.1. Thermodynamics
  • 1.2. Definitions
  • 1.3. Thermal Equilibrium and the Zeroth Law
  • 1.4. Temperature Scales
  • 1.5. Interactions between Systems and Surroundings
  • 1.6. Concluding Remarks
  • 1.7. Problems

Chapter 2. The Second Law and Equilibrium

  • 2.1. Thermal Efficiency
  • 2.2. Heat Engine
  • 2.3. Second Law of Thermodynamics
  • 2.4. The Concept of the Heat Engine: Derived by Analogy with a Hydraulic Device
  • 2.5. The Absolute Temperature Scale
  • 2.6. Entropy
  • 2.7. Representation of Heat Engines
  • 2.8. Reversibility and Irreversibility (first corollary of second law)
  • 2.9. Equilibrium
  • 2.10. Helmholtz Energy (Helmholtz Function)
  • 2.11. Gibbs Energy
  • 2.12. Gibbs Energy and Phases
  • 2.13. Examples of Different Forms of Equilibrium Met in Thermodynamics
  • 2.14. Concluding Remarks
  • 2.15. Problems

Chapter 3. Engine Cycles and their Efficiencies

  • 3.1. Heat Engines
  • 3.2. Air-Standard Cycles
  • 3.3. General Comments on Efficiencies
  • 3.4. Reversed Heat Engines
  • 3.5. Concluding Remarks
  • 3.6. Problems

Chapter 4. Availability and Exergy

  • 4.1. Displacement Work
  • 4.2. Availability
  • 4.3. Examples
  • 4.4. Available and Non-available Energy
  • 4.5. Irreversibility
  • 4.6. Graphical Representation of Available Energy and Irreversibility
  • 4.7. Availability Balance for a Closed System
  • 4.8. Availability Balance for an Open System
  • 4.9. Exergy
  • 4.10. The Variation of Flow Exergy for a Perfect Gas
  • 4.11. Concluding Remarks
  • 4.12. Problems

Chapter 5. Rational Efficiency of Power Plant

  • 5.1. The Influence of Fuel Properties on Thermal Efficiency
  • 5.2. Rational Efficiency
  • 5.3. Rankine Cycle
  • 5.4. Examples
  • 5.5. Concluding Remarks
  • 5.6. Problems

Chapter 6. Finite Time (or Endoreversible) Thermodynamics

  • 6.1. General Considerations
  • 6.2. Efficiency at Maximum Power
  • 6.3. Efficiency of Combined Cycle Internally Reversible Heat Engines when Producing Maximum Power Output
  • 6.4. Practical Situations
  • 6.5. More Complex Example of the Use of FTT
  • 6.6. Concluding Remarks
  • 6.7. Problems

Chapter 7. General Thermodynamic Relationships: for Single Component Systems or Systems of Constant Composition

  • 7.1. The Maxwell Relationships
  • 7.2. Uses of the Thermodynamic Relationships
  • 7.3. Tds Relationships
  • 7.4. Relationships between Specific Heat Capacities
  • 7.5. The Clausius–Clapeyron Equation
  • 7.6. Concluding Remarks
  • 7.7. Problems

Chapter 8. Equations of State

  • 8.1. Ideal Gas Law
  • 8.2. Van der Waals Equation of State
  • Problem
  • 8.3. Law of Corresponding States
  • 8.4. Isotherms or Isobars in the Two-phase Region
  • 8.5. Concluding Remarks
  • 8.6. Problems

Chapter 9. Thermodynamic Properties of Ideal Gases and Ideal Gas Mixtures of Constant Composition

  • 9.1. Molecular Weights
  • 9.2. State Equation for Ideal Gases
  • 9.3. Tables of u(T) and h(T) Against T
  • 9.4. Mixtures of Ideal Gases
  • 9.5. Entropy of Mixtures
  • 9.6. Concluding Remarks
  • 9.7. Problems

Chapter 10. Thermodynamics of Combustion

  • 10.1. Simple Chemistry
  • 10.2. Combustion of Simple Hydrocarbon Fuels
  • 10.3. Heats of Formation and Heats of Reaction
  • 10.4. Application of the Energy Equation to the Combustion Process – a Macroscopic Approach
  • 10.5. Combustion Processes
  • 10.6. Examples
  • 10.7. Concluding Remarks
  • 10.8. Problems

Chapter 11. Chemistry of Combustion

  • 11.1. Bond Energies and Heat of Formation
  • 11.2. Energy of Formation
  • 11.3. Enthalpy of Reaction
  • 11.4. Concluding Remarks

Chapter 12. Chemical Equilibrium and Dissociation

  • 12.1. Gibbs Energy
  • 12.2. Chemical Potential, µ
  • 12.3. Stoichiometry
  • 12.4. Dissociation
  • 12.5. Calculation of Chemical Equilibrium and the Law of Mass Action
  • 12.6. Variation of Gibbs Energy with Composition
  • 12.7. Examples of Significance of Kp
  • 12.8. The Van't Hoff Relationship between Equilibrium Constant and Heat of Reaction
  • 12.9. The Effect of Pressure and Temperature on Degree of Dissociation
  • 12.10. Dissociation Calculations for the Evaluation of Nitric Oxide
  • 12.11. Dissociation Problems with Two, or More, Degrees of Dissociation
  • 12.12. Concluding Remarks
  • 12.13. Problems

Chapter 13. Effect of Dissociation on Combustion Parameters

  • 13.1. Calculation of Combustion Both with and without Dissociation
  • 13.2. The Basic Reactions
  • 13.3. The Effect of Dissociation on Peak Pressure
  • 13.4. The Effect of Dissociation on Peak Temperature
  • 13.5. The Effect of Dissociation on the Composition of the Products
  • 13.6. The Effect of Fuel on Composition of the Products
  • 13.7. The Formation of Oxides of Nitrogen
  • 13.8. Concluding Remarks

Chapter 14. Chemical Kinetics

  • 14.1. Introduction
  • 14.2. Reaction Rates
  • 14.3. Rate Constant for Reaction, k
  • 14.4. Chemical Kinetics of NO
  • 14.5. Other Kinetics-Controlled Pollutants
  • 14.6. The Effect of Pollutants Formed Through Chemical Kinetics
  • 14.7. Concluding Remarks
  • 14.8. Problems

Chapter 15. Combustion and Flames

  • 15.1. Introduction
  • 15.2. Thermodynamics of Combustion
  • 15.3. Explosion Limits
  • 15.4. Flames
  • 15.5. Concluding Remarks
  • 15.6. Problems

Chapter 16. Reciprocating Internal Combustion Engines

  • 16.1. Introduction
  • 16.2. Further Considerations of Basic Engine Cycles
  • 16.3. Spark-Ignition Engines
  • 16.4. Diesel (Compression Ignition) Engines
  • 16.5. Friction in Reciprocating Engines
  • 16.6. Simulation of Combustion in Spark-Ignition Engines
  • 16.7. Concluding Remarks
  • 16.8. Problems

Chapter 17. Gas Turbines

  • 17.1. The Gas Turbine Cycle
  • 17.2. Simple Gas Turbine Cycle Analysis
  • 17.3. Aircraft Gas Turbines
  • 17.4. Combustion in Gas Turbines
  • 17.5. Concluding Remarks
  • 17.6. Problems

Chapter 18. Liquefaction of Gases

  • 18.1. Liquefaction by Cooling – Method (i)
  • 18.2. Liquefaction by Expansion – Method (ii)
  • 18.3. Concluding Remarks
  • 18.4. Problems

Chapter 19. Pinch Technology

  • 19.1. Heat Transfer Network without a Pinch Problem
  • 19.2. Step 1: Temperature Intervals
  • 19.3. Step 2: Interval Heat Balances
  • 19.4. Heat Transfer Network with a Pinch Point
  • 19.5. Step 3: Heat Cascading
  • 19.6. Problems

Chapter 20. Irreversible Thermodynamics

  • 20.1. Definition of Irreversible or Steady-State Thermodynamics
  • 20.2. Entropy Flow and Entropy Production
  • 20.3. Thermodynamic Forces and Thermodynamic Velocities
  • 20.4. Onsager's Reciprocal Relation
  • 20.5. The Calculation of Entropy Production or Entropy Flow
  • 20.6. Thermoelectricity – The Application of Irreversible Thermodynamics to a Thermocouple
  • 20.7. Diffusion and Heat Transfer
  • 20.8. Concluding Remarks
  • 20.9. Problems

Chapter 21. Fuel Cells

  • 21.1. Types of Fuel Cells
  • 21.2. Theory of Fuel Cells
  • 21.3. Efficiency of a Fuel Cell
  • 21.4. Thermodynamics of Cells Working in Steady State
  • 21.5. Losses in Fuel Cells
  • 21.6. Sources of Hydrogen for Fuel Cells
  • 21.7. Concluding Remarks
  • 21.8. Problems
Book details
ISBN: 9780444633736
Page Count: 578
Retail Price : £104.00
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Audience
Senior-level and graduate students studying thermodynamics; practicing engineers
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